Trent Alexander-Arnold faces a return to Liverpool in the Champions League.
The Reds will host Real Madrid and their former right-back at Anfield during the league phase of this season's competition.
It will mark Alexander-Arnold's first homecoming since leaving his boyhood club for the Spanish capital earlier this summer.
Meanwhile, Real Madrid are now managed by former Liverpool midfielder Xabi Alonso.
Arne Slot's side will also face Inter Milan and Atletico Madrid during the opening stage.
Arsenal face an unwanted reunion of their own with England captain Harry Kane as Bayern Munich visit the Emirates Stadium.
The former Tottenham striker can extend a stunning record against the Gunners after scoring 15 goals against them already in his career.
Elsewhere, the remaining Premier