Deep in the halls of the Australian War Memorial lies a collection of medals symbolising bravery so rare only 102 have been awarded in more than a century.

On the eve of Remembrance Day, Australians are being given a scarce glimpse in a new video recording shared with AAP of the largest assortment of the nation's highest military honour.

"The Victoria Cross, which ranks next to the George Cross, is considered the most prestigious award that can be bestowed on an individual for valour in the face of an enemy," Australian War Memorial director Matt Anderson says.

The memorial houses some 75 of 102 medals awarded to Australians, with just six given out since 1991, when Australia created its own VC separate from the British military honours system.

Previously, British military authorities

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